Determinación de parámetros cinéticos en la biosorción de Cromo (VI) en solución acuosa
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Keywords
Modelos cinéticos, ion metálico, cáscaras, remoción, Cromo (VI)
Resumen
La contaminación de cuerpos acuáticos por metales pesados es un problema ambiental creciente haciendo cada vez más importante el estudio y desarrollo de nuevas tecnologías y materiales que puedan ser usados para la remoción de este tipo de contaminantes. Así surge la adsorción usando materiales residuales como una alternativa sostenible para la solución de esta problemática. En el presente estudio se propone el uso de las cáscaras de plátano en la adsorción de Cr (VI) en un sistema por lotes estableciendo la cinética del proceso a diferentes condiciones de temperatura, tamaño de partícula y cantidad de adsorbente. El ajuste de los datos fue hecho usando los modelos teóricos de pseudo-primer orden, pseudo-segundo orden y Elovich. De los datos se establece que son los modelos de pesudo-segundo orden y Elovich los que muestran un mejor ajuste determinado así que la adsorción en el material se da sobre dos sitios de adsorción y que tal proceso está relacionado con una adsorción química. La máxima capacidad de adsorción de Cr (VI) fue encontrada a una condición de 0.0306 g, 0.6775 mm y 55°C a un tiempo de 420 min estableciendo el uso eficiente de cáscaras de plátano para la remoción del ion metálico en estudio.
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Referencias
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Article Details
Candelaria Tejada-Tovar, Universidad de Cartagena
Ingeniera Quimica; Magíster en Educación y Magíster en Ingenieria ambiental. Docente investigadora DEl GRupo IDAB (Investigación diseño de procesos y aprovechamiento de biomasas. Docente de Tiempo completo, categoria asociado de la Universidad de Cartagena.
Angel Villabona-Ortíz, Universidad de Cartagena
Universidad de Cartagena, Facultad de Ingeniería, Programa de Ingeniería Química, Departamento de Ingeniería Química, Grupo de Investigación en Diseño de procesos y Aprovechamiento de Biomsas (IDAB), avillabonao@unicartagena.edu.co, Cartagena, Colombia, https://orcid.org/0000-0001-8488-1076
Rodrigo Ortega-Toro, Universidad de Cartagena
Universidad de Cartagena, Facultad de Ingeniería, Programa de Ingeniería de Alimentos, Food Engineering Department, Food Packaging and Shelf Life Research Group (FP&SL), rortegap1@unicartagena.edu.co, Cartagena, Colombia.
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