Nopol Synthesis from Turpentine: Review of State of Art
Main Article Content
Keywords
nopol, turpentine, B-pinene, terpenes, terpenoids, Prins reaction.
Abstract
A review about nopol synthesis is included in this contribution. The traditional methodologies include the thermal synthesis and the use of ZnCl2 asa catalyst, and the emergent processes are the heterogeneous catalytic processes. The use of catalysts based on Sn supported on mesoporous materials, as reported by the Environmental Catalysis Research Group 10 years ago, iswidely discussed. Among the reported procedures, the homogeneous catalytic processes have the disadvantage of costs associated with separation andtreatment of inorganic salts generated during the processes. The commercial alternative for nopol production by heterogeneous catalytic processes should include reduction of costs associated with the production and regeneration of the catalysts. It should also include the minimization of the solvent required for compensating the requirements of time and energy associated with the thermal process with respect to the moderate reaction conditions of the heterogeneous catalytic processes.
MSC: 92.E20
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References
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[21] C. Corvi-Mora, “Derivative of (-)-6,6-dimethylbicyclo
[3.1.1]hept-2-ene-2-ethanolhaving mucosecretolytic activity, a process for its preparation and pharmaceuticalcompositions containing the same”, U.S. Patent US46440872003.Referenciado en 285
[22] S.Walker-Kahne, “Bacterial transglycosylases: assays for monitoring the activityusing Lipid ...”, U.S. Patent US6911318. Referenciado en 285
[23] E. Loginova, A. Mateeva, J. Dimitrov, G. Papanov, S. Iliev, P .Malakov, “Insecticidaleffect of byproducts of tobacco processing and essential oil manufacture”,Vissh Selskostopanski Institut “Vasil Kolarov” Plovdiv Nauchni Trudove, vol. 34,no. 3, 179-186, 1989. Referenciado en 285
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[25] A. Yang, Y. Leu, T. Hsueh, J. Hsueh, C. Huang, L. Rau, “Fragrant ink for ink-jetprinters”, U.S. Patent US6123757. Referenciado en 285
[26] E. Stevens, “Paint Stripping Compositions And Methods”, U.S. PatentUS559778819, jun-1995. Referenciado en 285
[27] J. Ziajka, W. Pasiuk-Bronikowska, “Autoxidation of sulphur dioxide in the presenceof alcohols under conditions related to the tropospheric aqueous phase”,Atmospheric Environment, vol. 37, n.o 28, pp. 3913-3922, sep. 2003.Referenciado en 286
[28] M. Bryjak, J. Kozlowski, P. Wieczorek, P. Kafarski, “Enantioselective transportof amino acid through supported chiral liquid membranes”, Journal of MembraneScience, vol. 85, n.o 3, pp. 221-228, dic. 1993. Referenciado en 286
[29] A. Morway, “Grease process utilizing the alkali fusion products of cyclic alcohols”,U.S. Patent 280197408-jun-1957. Referenciado en 286
[30] S. Dershem, “Resinless pseudoplastic bonding compositions”, U.S. Patent53063331994. Referenciado en 286
[31] A. Gilbert, N. Allen, “Polymer photochemistry”, in Photochemistry, vol. 26,Cambridge: The Royal Society of chemistry, pp. 361-426, 1995.Referenciado en 286
[32] E. Drioli, E. Giorno, Biocatalytic Membrane Reactors: Applications in Biotechnologyand the Pharmaceutical Industry. CRC PressINC, 1999.Referenciado en 286
[33] L. Paquette, Handbook of Reagents for Organic Synthesis, Chiral Reagents forAsymmetric Synthesis. Chichester, UK: John Wiley & Sons, 2003.Referenciado en 286
[34] V. Saroglou, N. Dorizas, Z. Kypriotakis, y H. Skaltsa, “Analysis of the essentialoil composition of eight Anthemis species from Greece”, J Chromatogr A, vol.1104, n.o 1-2, pp. 313-322, feb. 2006. Referenciado en 286
[35] T. Ke-wen, C. Guo-bin, “Analysis of Chemical Component of Volatile Oil FromTurmeric by Gas Chromatography-Mass Spectrometry”, Journal of Chinese MassSpectrometry Society, vol. 25, n.o 3, pp. 163-165, 2004. Referenciado en 286
[36] S. Cheng, H. Lin, S. Chang, “Chemical composition and antifungal activity ofessential oils from different tissues of Japanese Cedar (Cryptomeria japonica)”,J. Agric. Food Chem., vol. 53, n.o 3, pp. 614-619, feb. 2005. Referenciado en 286
[37] “Port Orford Cedar, Chamaecyparis lawsoniana essential oil”, Oshadhi Ltd.
[Online].Available: http://www.oshadhi.co.uk/port-orford-cedar-chamaecyparis-lawsoniana/.Referenciado en 286
[38] M. Ucar, “Composition of sulfate turpentine from Turkey”, European Journal ofWood and Wood Products, vol. 58, n.o 4, pp. 292-293, 2000. Referenciado en 286
[39] D. Alabran, H. Moskowitz, A. Mabrouk, “Carrot-root oil components and theirdimensional characterization of aroma”, J. Agric. Food Chem., vol. 23, n.o 2, pp.229-232, mar. 1975. Referenciado en 286
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[43] E. Alarcón, A. Villa, C. de Correa, “Efecto de las condiciones de síntesis hidrotérmicade Sn-MCM-41 en la producción de nopol”, Revista Facultad de IngenieríaUniversidad de Antioquia, n.o 49, pp. 19-29, 2009. Referenciado en 287, 291, 295
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