Síntesis de nopol a partir de trementina: revisión del estado del arte
Main Article Content
Keywords
nopol, trementina, beta-pineno, terpenos, terpenoides, reacción de Prins.
Resumen
En esta contribución se hace una revisión de los métodos para la síntesis del nopol. Los procesos convencionales abarcan la síntesis térmica y la catalítica con ZnCl2 y los emergentes corresponden a los catalíticos heterogéneos. Se destaca el uso de catalizadores de Sn soportado en materiales mesoporosos producto de las investigaciones de la última década en el Grupo Catálisis Ambiental. La evaluación de las tecnologías existentes de producción de nopol muestra ventajas de la síntesis térmica y la catálisis heterogénea frenteal uso de ZnCl2, especialmente por los costos potenciales en la separación y tratamiento de las sales inorgánicas. No obstante, cualquier intento de obtener una alternativa comercial de la tecnología reciente debería reducir los costos requeridos en la producción y regeneración del material catalítico y minimizar el requerimiento de solvente, con el fin que las condiciones moderadas de reacción de la catálisis heterogénea compense adecuadamente los requerimientos energéticos y de tiempo del proceso térmico.
MSC: 92.E20
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[21] C. Corvi-Mora, “Derivative of (-)-6,6-dimethylbicyclo
[3.1.1]hept-2-ene-2-ethanolhaving mucosecretolytic activity, a process for its preparation and pharmaceuticalcompositions containing the same”, U.S. Patent US46440872003.Referenciado en 285
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[24] G.Dufau, A. Querrioux, G. Molla, M. Barsacq. “Use of terpenes as pesticide andplant nutrient formulation adjuvants with foliar retention-increasing activity”,Europe Patent No. FR2828064, 2003. Referenciado en 285
[25] A. Yang, Y. Leu, T. Hsueh, J. Hsueh, C. Huang, L. Rau, “Fragrant ink for ink-jetprinters”, U.S. Patent US6123757. Referenciado en 285
[26] E. Stevens, “Paint Stripping Compositions And Methods”, U.S. PatentUS559778819, jun-1995. Referenciado en 285
[27] J. Ziajka, W. Pasiuk-Bronikowska, “Autoxidation of sulphur dioxide in the presenceof alcohols under conditions related to the tropospheric aqueous phase”,Atmospheric Environment, vol. 37, n.o 28, pp. 3913-3922, sep. 2003.Referenciado en 286
[28] M. Bryjak, J. Kozlowski, P. Wieczorek, P. Kafarski, “Enantioselective transportof amino acid through supported chiral liquid membranes”, Journal of MembraneScience, vol. 85, n.o 3, pp. 221-228, dic. 1993. Referenciado en 286
[29] A. Morway, “Grease process utilizing the alkali fusion products of cyclic alcohols”,U.S. Patent 280197408-jun-1957. Referenciado en 286
[30] S. Dershem, “Resinless pseudoplastic bonding compositions”, U.S. Patent53063331994. Referenciado en 286
[31] A. Gilbert, N. Allen, “Polymer photochemistry”, in Photochemistry, vol. 26,Cambridge: The Royal Society of chemistry, pp. 361-426, 1995.Referenciado en 286
[32] E. Drioli, E. Giorno, Biocatalytic Membrane Reactors: Applications in Biotechnologyand the Pharmaceutical Industry. CRC PressINC, 1999.Referenciado en 286
[33] L. Paquette, Handbook of Reagents for Organic Synthesis, Chiral Reagents forAsymmetric Synthesis. Chichester, UK: John Wiley & Sons, 2003.Referenciado en 286
[34] V. Saroglou, N. Dorizas, Z. Kypriotakis, y H. Skaltsa, “Analysis of the essentialoil composition of eight Anthemis species from Greece”, J Chromatogr A, vol.1104, n.o 1-2, pp. 313-322, feb. 2006. Referenciado en 286
[35] T. Ke-wen, C. Guo-bin, “Analysis of Chemical Component of Volatile Oil FromTurmeric by Gas Chromatography-Mass Spectrometry”, Journal of Chinese MassSpectrometry Society, vol. 25, n.o 3, pp. 163-165, 2004. Referenciado en 286
[36] S. Cheng, H. Lin, S. Chang, “Chemical composition and antifungal activity ofessential oils from different tissues of Japanese Cedar (Cryptomeria japonica)”,J. Agric. Food Chem., vol. 53, n.o 3, pp. 614-619, feb. 2005. Referenciado en 286
[37] “Port Orford Cedar, Chamaecyparis lawsoniana essential oil”, Oshadhi Ltd.
[Online].Available: http://www.oshadhi.co.uk/port-orford-cedar-chamaecyparis-lawsoniana/.Referenciado en 286
[38] M. Ucar, “Composition of sulfate turpentine from Turkey”, European Journal ofWood and Wood Products, vol. 58, n.o 4, pp. 292-293, 2000. Referenciado en 286
[39] D. Alabran, H. Moskowitz, A. Mabrouk, “Carrot-root oil components and theirdimensional characterization of aroma”, J. Agric. Food Chem., vol. 23, n.o 2, pp.229-232, mar. 1975. Referenciado en 286
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